High solids low volatile organic compounds content ethylene propylene diene terpolymer formulation

ABSTRACT

A two part low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter, wherein a first component has EPDM, a solvent, a curative, an additive, and a blend of a pigment and a filler. The second component contains solvent and a metal drier. The invention includes a method for making the coating and a cured coated substrate with the cured waterproof rubber coating disposed thereon.

CROSS REFERENCE TO RELATED APPLICATIONS

The present application claims priority to and the benefit of co-pending U.S. Provisional Patent Application Ser. No. 61/764,471 filed on Feb. 13, 2013, entitled “AMBIENT LIGHT CURABLE ETHYLENE PROPYLENE DIENE MONOMER RUBBER COATING DEVOID OF THERMALLY ACTIVATED ACCELERATORS”; co-pending U.S. Provisional Patent Application Ser. No. 61/764,479 filed on Feb. 13, 2013, entitled “DUAL CURABLE ETHYLENE PROPYLENE DIENE MONOMER RUBBER COATING USING A PHOTOINITIATOR AND A PEROXIDE”; and co-pending U.S. Provisional Patent Application Ser. No. 61/764,483 filed on Feb. 13, 2013, entitled “HIGH SOLIDS LOW VOC CONTENT ETHYLENE PROPYLENE DIENE RUBBER COATING.” These references are hereby incorporated in their entirety.

FIELD

The present embodiments generally relate to a two part low volatile organic compounds content curable ethylene propylene diene terpolymer rubber coating compositions that are consumer friendly to use.

BACKGROUND

A need exists for a two part ambient temperature waterproof rubber coating that requires no additional heat for curing.

A further need exists for a two part ethylene propylene diene terpolymer (EPDM) waterproof rubber coating formed from a liquid that does not require isocyanates or similar toxic chemicals.

A need exists for a two part formulation that can be applied to existing roofs and existing substrates as a “cool white easily applied waterproof rubber coating” to lower the costs of energy and reduce maintenance costs of a facility.

The present embodiments meet these needs.

DETAILED DESCRIPTION OF THE EMBODIMENTS

Before explaining the present invention in detail, it is to be understood that the invention is not limited to the particular embodiments and that it can be practiced or carried out in various ways.

The present embodiments relate to a two part low volatile organic compounds curable ethylene propylene diene terpolymer formulation that are consumer friendly to use.

The present embodiments relate to a formulation for a durable curable waterproof liquid rubber coating with a solids content of at least 60 percent solids by volume based on the total coating formulation.

A benefit of the formulation is that the two part liquid EPDM formulation liquid rubber coating produced from the method is ambient temperature curable.

A benefit of the formulation is the two part liquid EPDM formulation is easy to apply in the field since it is a liquid and no heat source is needed to cure the formulation.

A benefit of the formulation is that users of the liquid EPDM formulation produced from the method will avoid the possibility of having second or third degree burns from applying the two part formulation, because the coating is “heat free” to cure on a substrate which can be a roofing tile or flat roof base material. The formulation produced from the method does not “hold heat” but reflects heat.

A two part liquid EPDM formulation produced from the method creates a cured coating that has (1) waterproof sealing to resist hurricane strength rainfall; (2) resistance to acid rain degradation allowing at least 15 years useful life for a roof in an acid rain area (3) ability to withstand cold temperatures of down to −50 degrees Centigrade, such as Arctic weather.

A two part durable curable waterproof rubber liquid coating formulation produced from the method does not require isocyanates or similar toxic curing agents which are known to have a harmful effect on people as evidenced by allergic sensitization to isocyanates.

A two part durable curable waterproof liquid rubber coating formulation produced from the method can be applied to existing roofs and existing substrates as a “cool white roof” material lowering the cost of building maintenance, lowering the cost of energy, and reducing the dependence of the United States on foreign oil.

Schools, hospitals, public housing facilities, warehouses, residential homes, and facilities for the elderly, would benefit from a durable curable waterproof liquid rubber coating formulation produced from the method on the roofs of their institutions because the material will remain cool while simultaneously sealing the roof, providing a reflective surface to reduce costs of energy and costs of maintaining the facilities.

A cured material produced from the method can extend the life of a roof, reducing the need for roof replacement.

In other embodiments, a formulation produced from the method can be used to seal docks for marinas.

A benefit of a durable curable waterproof liquid rubber coating formulation produced from the method is that the formulation produced from the method is stable in its packaging system for delivery to a user.

The following terms are used herein:

The term “active heating” as used herein can refer to the external addition of energy to the formulation by the use of heat generating devices, such as adding energy through mechanical means with heated application hoses, infrared lamps, heat guns, or by adding heat using an extruder.

The term “additive” as used herein can refer to an antioxidant, an ultraviolet light stabilizer, or combinations thereof.

The term “adhesion promoter” as used herein can refer to a component made from molecules that tie the formed ambient light curable EPDM coating to a substrate for enhanced bonding. An example of an adhesion promoter can be SARET® 633 or 634 made by Arkema France.

The term “air release agent” can refer to mineral oil, paraffinic oil, silicone oil, or similar oil. An example of paraffinic oil can be FHR ULTRA® made by Flint Hills Resources of Wichita, Kans., an example of a mineral oil can be UNIQFORM™ made by UniqChem UK Co., Ltd., and an example of an air release agent can be BYK®-320 made by BYK-Chemie GmbH of Germany.

The term “ambient light” as used herein can refer to visible, ultraviolet or near infrared light. The range of wavelength from ultraviolet to near infrared light can range in wavelength from 200 nanometers to 1500 nanometers.

The term “ambient temperature” as used herein can refer to a temperature less than 50 degrees Celsius and equal to or greater than −10 degrees Celsius.

The term “antioxidant” can refer to a hindered phenolic stabilizer, such as IRGANOX® 1076 made by Ciba Specialty Chemicals Corporation of Tarrytown, N.Y.

The term “anti-settling agent” as used herein can refer to an agent that prevents the settling of pigments and fillers in a liquid formulation. An example of a usable anti-Attorney settling agent can be M-P-A® made by Elementis Specialties, Inc. of Hightstown, N.J. Another example is a hydroxyethyl cellulose. Still another example is a fumed silica.

The term “biocide” can be a variety of ingredients. A methylchloroisothiazolinone, such as MERGAL® K9N made by Troy Corporation or ROCIMA™ 363 available from Dow Chemical of Midland, Mich. can be used.

The term “co-agent” as the term is used herein can refer to a reactive molecule with two or more functional groups, for bonding with an EPDM molecule. The co-agent can enhance crosslinking between two EPDM molecules initiated by a photoinitiator. The term “enhances” can refer to an accelerated process of crosslinking. Co-agent accelerates reaction of the free radicals with the active sites of the unsaturated diene to cross link the terpolymer.

Usable co-agents can include an acrylate such as hexane diol diacrylate, polybutadiene acrylate, a triallyl cyanurate, polybutadiene, and phenylenedimaleimide known as VAMAC® DP HVA-2 available from E.I. DuPont of Wilmington, Del.

The term “defoamer” as used herein can refer to components, such as polymethyl alkyl siloxane. An example of a defoamer can be BYK®-A500 defoamer. Defoamers can include modified polysiloxane or polymethylsiloxane in solvents such as BYK®-066 N or BYK®-052 made by BYK-Chemie GmbH of Germany.

The term “flame retardant” as referred to herein can refer to a liquid or a powder flame retardant. The powdered version can be used in the method at a different blending point than the liquid version. An example of a flame retardant usable herein is alumina trihydrate. Flame retardants can be used as fillers in this invention. Flame retardants can be used as pigments in this invention.

The term “inert atmosphere” as used herein can refer to an atmosphere placed over the reaction using an inert gas such as nitrogen or argon.

The term “low shear” as used herein can refer to mixing at a blade tip speed of less than 2500 linear feet per minute used in the mixing device.

The term “molecular weight” for the polymer as used herein can refer to a weight average molecular weight as determined by gel permeation chromatography (GPC) measurement.

The term “photoinitiator” as used herein can refer to photoinitiators that are devoid of thermally activated accelerators.

Usable photoinitiators include type I photoinitiators which can include: bis(2,4,6-trimethylbenzoyl)-phenyl phosphineoxide, known as IRGACURE® 819 and 1-hydroxy-cyclohexyl-phenyl-ketone known as IRGACURE® 184 made by BASF Corporation.

Type II photoinitiators can be usable and can include benzophenone, alpha hydroxyl ketone, alpha amino ketone, isothioxanthone, and combinations thereof. All photoinitiators can remain devoid of thermally activated accelerators.

The term “pigment dispersant” can refer to a chemical that allows pigment to remain homogenously dispersed in the coating. Examples of usable pigment dispersants include NUOSPERSE® 9100 available from Elementis Specialties, Inc.

The term “plant-based solvent” can refer to vegetable based, grass based, weed based, nut based, or food based solvents including but not limited to methyl soyate. Only solvents that dissolve EPDM or one of the other polymers are usable herein.

The term “plasticizer” as used herein can refer to non-volatile plasticizers, including paraffinic oil, silicone oil, naphthenic oil, plant based oil, diester oil, mineral oil, a low molecular weight polyalpha olefin, or combinations thereof.

The term “surfactant” as used herein can refer to a diester sulfosuccinate and polysorbates, and combinations thereof.

The term “terpolymer” as used herein can refer to a polymer of ethylene, propylene, and one or more non-conjugated dienes. Examples of non-conjugated diene usable herein can include norbornene, ethylidene norbornene, 1,4, hexadiene, dicyclopentadiene, vinyl norbornene, methylene norbornene, and combinations thereof.

In other embodiments, the terpolymer of ethylene, propylene and one or more non-conjugated dienes can have the propylene replaced by another alpha olefin, such as but not limited to 1-butene, 1-pentene, 1-hexene, 1-heptene, 1-octene, or combinations thereof.

In embodiments, the “polymer” can be ethylene propylene polymer, ethylene butene polymer, ethylene pentene polymer, or combinations thereof.

“Solvents” as the term is used herein can refer to an aliphatic solvent, an aromatic solvent, or a plant based solvent with a density from 0.6 to 1.2 grams per cubic centimeter. Examples of usable solvents include mineral spirits, toluene, hexane, xylene, hexamethyldi-siloxane, or combinations thereof.

The term “thermally activated accelerator” as the term is used herein can refer to accelerators which require temperatures above ambient temperatures to cure an EPDM coating and specifically require “active heating.”

In a formulation produced by the method, no thermally activated accelerators are used, which is a feature of this method.

The term “ultraviolet stabilizers” can refer to chemicals such as hindered amine light stabilizers, benzotriazoles, or similar components.

The term “waterproof” as used herein can refer to a moisture vapor permeation rating of less than 1.

The term “wetting agent” can refer to chemicals such as DISPONER™ 983 available from Elementis Specialties, Inc.

Wetting agents can include silicone polyacrylate copolymer in solvents such as BYK®-3550 or a solvent-free polyether modified dimethylpolysiloxane such as BYK®-378 made by BYK-Chemie GmbH of Germany.

A formulation produced by the method can be coated onto various substrates. Substrates that are usable with this formed ambient light curable waterproof liquid rubber coating can include roofs, aged PVC materials, aged EPDM roofing materials, aged thermoplastic olefin materials, metal, glass, car port roofs, docks, concrete, polyurethane foam, acrylate material system, wood, oil rig mats, and high impact devices.

A benefit of a formulation produced by the method is that it can cure in the rain.

The invention relates to a low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

The formulation includes an ethylene propylene diene terpolymer component.

The ethylene propylene diene terpolymer component contains a first portion of ethylene propylene diene terpolymer (EPDM).

The ethylene propylene diene terpolymer (EPDM) is 50 weight percent to 99 weight percent of a total amount of the ethylene propylene diene terpolymer (EPDM) used in the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

The ethylene propylene diene terpolymer component contains a first portion of solvent.

The first portion of solvent is 33 weight percent to 67 weight percent of a total amount of solvent used in the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

The ethylene propylene diene terpolymer component contains a second portion of ethylene propylene diene terpolymer (EPDM).

The second portion of ethylene propylene diene terpolymer (EPDM) is 0.1 weight percent to 50 weight percent of the total amount of ethylene propylene diene terpolymer (EPDM) in the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

The ethylene propylene diene terpolymer component contains a second portion of solvent.

The second portion of solvent is 33 weight percent to 67 weight percent of the total amount of solvent in the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

The ethylene propylene diene terpolymer component contains 0.01 weight percent to 10 weight percent of a co-agent.

The weight percent of the co-agent is based on a total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

The co-agent can be an acrylate, a triallyl cyanurate, a polybutadiene, and a phenylenedimaleimide.

The ethylene propylene diene terpolymer component contains 0.1 weight percent to 15 weight percent of a peroxide.

The weight percent of the peroxide is based on a total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

The peroxide can be a peroxyketal, a peroxyester, a dialkyl peroxide, a peroxy carbonate, and an azo initiator;

The formulation includes a catalyst component.

The catalyst component contains 0.1 weight percent to 10 weight percent of a metal drier based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

The metal drier can be a metal carboxylate, and a metal alkoxide.

The catalyst component contains 1 weight percent to 5 weight percent of a solvent based on the total weight of the solvent in the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

The solvent can be an aliphatic solvent, an aromatic solvent, and a plant-based solvent.

The ethylene propylene diene terpolymer component and catalyst component form a blend, with a weight ratio from 250:1 to 10:1 of the ethylene propylene diene terpolymer component to the catalyst component.

The blend is adapted to cure on a substrate without addition of another curative, producing a low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter with a tensile strength greater than 250 psi, an elongation greater than 50 percent, and a Shore A hardness from 40 to 70.

In embodiments, the first portion of ethylene propylene diene terpolymer (EPDM) can have a different molecular weight than the second portion of ethylene propylene diene terpolymer (EPDM).

In embodiments, the formulation includes 50 weight percent to 99 weight percent of a pigment based on a low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

In embodiments, the amount of the pigment represents a total weight percent of pigment and the pigment has a particle dispersion from 4 to 8 units on the Hegman scale.

In embodiments, the formulation includes 50 weight percent to 99 weight percent of a filler based on a total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

In embodiments, the amount of the filler added represents a total weight percent of filler and the filler has a particle dispersion from 4 to 8 units on the Hegman scale.

In embodiments, the formulation includes 0.1 weight percent to 10 weight percent of an additive based on a total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

In embodiments, the additive can be a hindered phenolic stabilizer or a hindered amine ultraviolet stabilizer.

In embodiments, the formulation includes 0.1 weight percent to 10 weight percent of an adhesion promoter based on the total weight low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

In embodiments, the adhesion promoter can be a zinc diacrylate or zinc dimethacrylate.

In embodiments, the formulation includes 0.1 weight percent to 10 weight percent of a pigment dispersant based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

In embodiments, the pigment dispersant can be 1 methoxy-2-propylacetate.

In embodiments, the formulation includes 0.1 weight percent to 10 weight percent of an anti-settling agent based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

In embodiments, the anti-settling agent can be a hydroxyl ethyl cellulose and a fumed silica.

In embodiments, the formulation includes 0.1 weight percent to 10 weight percent of a defoamer based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

In embodiments, the defoamer can be a polymethyl alkyl siloxane, a modified polysiloxane, and a polymethylsiloxane in a solvent.

In embodiments, the formulation includes 0.1 weight percent to 10 weight percent of an air release agent based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

In embodiments, the air release agent can be a mineral oil, a paraffinic oil, a silicone oil, or a similar oil.

In embodiments, the formulation includes 0.1 weight percent to 30 weight percent of a flame retardant based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

In embodiments, the flame retardant can be an alumina trihydrate.

In embodiments, the formulation includes 0.1 weight percent to 12 weight percent of a wetting agent based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

In embodiments, the wetting agent can be a silicone polyacrylate copolymer in solvent and a solvent-free polyether modified dimethylpolysiloxane.

In embodiments, the formulation includes 0.1 weight percent to 5 weight percent of a biocide based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

In embodiments, the biocide can be a methylchloroisothiazolinone.

In embodiments, the formulation includes 0.1 weight percent to 30 weight percent of a low molecular weight non-volatile plasticizer based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

In embodiments, the plasticizer can be a paraffinic oil, a naphthenic oil, a plant based oil, a diester oil, a silicone oil, a mineral oil, a low molecular weight polyalphaolefin, or combinations thereof.

In embodiments, the solvents can be selected from the group: mineral spirits and hexamethyldi-siloxane.

The following procedure relates to a coating compound order of addition for the 2 part method forming a liquid rubber formulation.

For the first part of the method, known as the ethylene propylene diene terpolymer component, mix in a vessel 50 percent of the total formulation amount of EPDM polymer and 50 percent of the total formulation amount of solvent used in the ethylene propylene diene terpolymer component.

Next, mix the components at a temperature from 20 degrees Celsius to 50 degrees Celsius until a smooth homogenous solution is formed.

As a third step, add the remaining 50 percent of the total formulation amount of EPDM to the solution and continue mixing at a temperature from 20 degrees Celsius to 50 degrees Celsius until all of the EPDM is thoroughly mixed forming a smooth viscous solution. Typically the viscosity should be from 15,000 centipoise to 60,000 centipoise.

As a fourth step, slowly add 100 percent of the total formulation amount of filler and 100 percent of the total formulation amount of pigment into this smooth viscous solution.

As a fifth step, mix at a temperature of from 20 degrees Celsius to 50 degrees Celsius until the mixture forms a smooth grind base. The grind base is high shear mixed to from 4 to 8 on the Hegman scale.

As a sixth step, add to the grind base the remaining 50 percent of the total formulation amount of solvent used in the ethylene propylene diene terpolymer component and 100 percent of the total formulation amount of plasticizers.

As a seventh step, mixing at a temperature from 20 degrees Celsius to 50 degrees Celsius until all of the solvent and plasticizers are thoroughly incorporated into the solution.

As an eighth step, add in 100 percent of the total formulation amount of at least one of the additives, co-agents, wetting agents, defoamers, surfactants, flame retardants, air release agents, biocides, anti-settling agents, pigment dispersants, and adhesion promoters.

As a ninth step, mixing at a temperature from 20 degrees Celsius to 50 degrees Celsius until all of the additives, co-agents, wetting agents, defoamers, surfactants, flame retardants, air release agents, biocides, anti-settling agents, pigment dispersants, and adhesion promoters are thoroughly incorporated into the solution and the solution is from 4 to 8 on the Hegman scale.

As a tenth step, add 100 percent of the total formulation amount of peroxide curatives.

As an eleventh step, mixing at a temperature from 20 degrees Celsius to 50 degrees Celsius until all of the components are thoroughly incorporated into the solution and the particulate in the solution is from 4 to 8 on the Hegman scale.

For the catalyst component, into a separate vessel prepare a solution of 100 percent of the solvent used in the catalyst component and 100 percent of the metal driers.

Next, mix the solvent and the metal driers at a temperature from 20 degrees Celsius to 50 degrees Celsius until thoroughly mixed into the solution.

At the time of application to the substrate, mix the catalyst component with the ethylene propylene diene terpolymer component.

The following tables represent formulations which can be created with this invention.

Example 1

High Solids Coating Example Component Masterbatch Mix % EPDM Terpolymer T-5131 (3216 Mw) lot GE2F305 41.77 Pigment Kronos 2300 TiO₂ 5.90 Filler Jetfil 200 Talc 9.83 Boicide Zinc Oxide XX-601R 2.21 Solvent Mineral Spirits 29.49 Co-agent SR 238 2.21 Addiitive Tinuvin 1130 0.15 Additive Tinuvin 292 0.14 Plasticizer Dow Corning 200 Fluid 0.30 Curative TBPB 0.88 Curative Luperox 231 0.15 Part B Metal Dryer Cobalt Naphthenate 12% 1.23 MetalDryer 18% Zinc Ten-Cem 3.28 Solvent Mineral Spirits 2.46 Total 100.00

Example 2

Job 1006-74 Component Ingredient % EPDM Terpolymer Trilene 65 26.74 Pigment Kronos 2300 TiO2 10.70 Filler Jetfil 200 Talc 19.92 Biocide Zinc Oxide XX-601R 2.01 Solvent Mineral Spirits 32.39 Co-agent SR 238 2.01 Additive Tinuvin 1130 0.13 Additive Tinuvin 292 0.13 Plasticizer Dow Corning 200 Fluid 0.27 Curative TBPB 0.40 Curative Varox 231 0.07 Part B Metal Drier Cobalt Naphthenate 12% 1.11 Metal Drier 18% Zinc Ten-Cem 2.97 Solvent Odorless Mineral Spirits 1.15 Viscosity (cP) 9480 VOC (gms/L) 374

Example 3

Component Ingredient % EPDM Terpolymer Trilene 65 24.89 Plasticizer Ultra 1199 Oil 7.47 Pigment Tronox 8400 9.96 Filler Burgess Optiwhite Clay 16.18 Biocide Zinc Oxide 1.87 Additive MPA 1078X 0.62 Solvent Toluene 0.62 Additive TMQ 0.07 Additive Lowlite 26 0.12 Additive Lowlite 77 0.12 Surfacant Tween 85 0.25 Co-agent SR 238 1.87 Pigment Ultramarine Blue 5008 0.10 Pigment Mineral Spirits 31.37 Plasticizer Dow Corning 200 Fluid 0.25 Curative TBPB 0.25 Part B Metal Drier 6% Cobalt Naphthenate 1.00 Metal Drier Octoate Z 0.25 Metal Drier Catalyst 320 0.25 Solvent Mineral Spirits 2.49

Example 4

Formulation with Defoamer Component Ingredient % EPDM Polymer Trilene 5131 41.77 Pigment Kronos 2300 TiO₂ 1.90 Filler Jetfil 200 Talc 5.83 Boicide Zinc Oxide XX-601R 0.21 Solvent Mineral Spirits 29.49 Co-agent SR 238 2.21 Addiitive Tinuvin 1130 0.15 Additive Tinuvin 292 0.14 Plasticizer Dow Corning 200 Fluid 0.30 Curative TBPB 0.88 Curative Luperox 231 0.15 Defoamer BYK 052 10.00 Part B Metal Dryer Cobalt Naphthenate 12% 1.23 MetalDryer 18% Zinc Ten-Cem 3.28 Solvent Mineral Spirits 2.46

Example 5

Formulation with Anti-Settling Agent Component Ingredient % EPDM Polymer Trilene 5131 41.77 Pigment Kronos 2300 TiO₂ 1.90 Filler Jetfil 200 Talc 5.83 Boicide Zinc Oxide XX-601R 0.21 Solvent Mineral Spirits 29.49 Co-agent SR 238 2.21 Addiitive Tinuvin 1130 0.15 Additive Tinuvin 292 0.14 Plasticizer Dow Corning 200 Fluid 0.30 Curative TBPB 0.88 Curative Luperox 231 0.15 Anti-Settling Agent MPA 1078 10.00 Part B Metal Dryer Cobalt Naphthenate 12% 1.23 Metal Dryer 18% Zinc Ten-Cem 3.28 Solvent Mineral Spirits 2.46

Example 6

Formulation with Flame Retardant Component Ingredient % EPDM Polymer Trilene 5131 36.77 Pigment Kronos 2300 TiO₂ 0.90 Filler Jetfil 200 Talc 0.83 Boicide Zinc Oxide XX-601R 2.21 Solvent Mineral Spirits 18.49 Co-agent SR 238 2.21 Addiitive Tinuvin 1130 0.15 Additive Tinuvin 292 0.14 Plasticizer Dow Corning 200 Fluid 0.30 Curative TBPB 0.88 Curative Luperox 231 0.15 Flame Retardant ATH 30.00 Part B Metal Dryer Cobalt Naphthenate 12% 1.23 MetalDryer 18% Zinc Ten-Cem 3.28 Solvent Mineral Spirits 2.46

Example 7

Formulation with Pigment Dispersant Component Ingredient % EPDM Polymer Trilene 5131 41.77 Pigment Kronos 2300 TiO₂ 1.90 Filler Jetfil 200 Talc 5.83 Boicide Zinc Oxide XX-601R 0.21 Solvent Mineral Spirits 29.49 Co-agent SR 238 2.21 Addiitive Tinuvin 1130 0.15 Additive Tinuvin 292 0.14 Plasticizer Dow Corning 200 Fluid 0.30 Curative TBPB 0.88 Curative Luperox 231 0.15 Pigment Dispersant Nuosperse 9100 10.00 Part B Metal Dryer Cobalt Naphthenate 12% 1.23 Metal Dryer 18% Zinc Ten-Cem 3.28 Solvent Mineral Spirits 2.46

Example 8

Formulation with Biocide Component Ingredient % EPDM Polymer Trilene 5131 41.77 Pigment Kronos 2300 TiO₂ 2.90 Filler Jetfil 200 Talc 7.83 Boicide Zinc Oxide XX-601R 2.21 Solvent Mineral Spirits 24.49 Co-agent SR 238 2.21 Addiitive Tinuvin 1130 0.15 Additive Tinuvin 292 0.14 Plasticizer Dow Corning 200 Fluid 0.30 Curative TBPB 0.88 Curative Luperox 231 0.15 Biocide Mergal K9N 10.00 Part B Metal Dryer Cobalt Naphthenate 12% 1.23 Metal Dryer 18% Zinc Ten-Cem 3.28 Solvent Mineral Spirits 2.46

Example 9

Formulation with Adhesion Promoter Component Ingredient % EPDM Polymer Trilene 5131 41.77 Pigment Kronos 2300 TiO₂ 1.90 Filler Jetfil 200 Talc 5.83 Boicide Zinc Oxide XX-601R 0.21 Solvent Mineral Spirits 29.49 Co-agent SR 238 2.21 Addiitive Tinuvin 1130 0.15 Additive Tinuvin 292 0.14 Plasticizer Dow Corning 200 Fluid 0.30 Curative TBPB 0.88 Curative Luperox 231 0.15 Adhesion Promoter SR 634 10.00 Part B Metal Dryer Cobalt Naphthenate 12% 1.23 Metal Dryer 18% Zinc Ten-Cem 3.28 Solvent Mineral Spirits 2.46

Example 10

Formulation with Air Release Component Ingredient % EPDM Polymer Trilene 5131 41.77 Pigment Kronos 2300 TiO₂ 1.90 Filler Jetfil 200 Talc 5.83 Boicide Zinc Oxide XX-601R 0.21 Solvent Mineral Spirits 29.49 Co-agent SR 238 2.21 Addiitive Tinuvin 1130 0.15 Additive Tinuvin 292 0.14 Plasticizer Dow Corning 200 Fluid 0.30 Curative TBPB 0.88 Curative Luperox 231 0.15 Air Release Agent Ultra 1199 10.00 Part B Metal Dryer Cobalt Naphthenate 12% 1.23 Metal Dryer 18% Zinc Ten-Cem 3.28 Solvent Mineral Spirits 2.46

Example 11

Formulation with Wetting Agent Component Ingredient % EPDM Polymer Trilene 5131 41.77 Pigment Kronos 2300 TiO2 1.90 Filler Jetfil 200 Talc 5.83 Boicide Zinc Oxide XX-601R 0.21 Solvent Mineral Spirits 29.49 Co-agent SR 238 2.21 Addiitive Tinuvin 1130 0.15 Additive Tinuvin 292 0.14 Plasticizer Dow Corning 200 Fluid 0.30 Curative TBPB 0.88 Curative Luperox 231 0.15 Wetting Agent BYK 378 10.00 Part B Metal Dryer Cobalt Naphthenate 12% 1.23 Metal Dryer 18% Zinc Ten-Cem 3.28 Solvent Mineral Spirits 2.46

A formulation produced by the method is a two part system, that is, a two component formulation which when the two components are blended together, cure over a substrate, forming a waterproof cured rubber coating.

The embodiments further relate to a method for making a durable curable waterproof liquid rubber coating with a solids content of at least 60 percent solids by volume of the total coating formulation.

The method involves as a first step, blending in a closed vessel forming a solution, a first portion of ethylene propylene diene terpolymer (EPDM) with a first portion of solvent.

The ethylene propylene diene terpolymer (EPDM) is 50 weight percent to 99 weight percent of a total amount of the ethylene propylene diene terpolymer (EPDM) used in the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

The first portion of solvent is 33 weight percent to 67 weight percent of a total amount of solvent used in the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

The second step involves mixing the solution in a high shear mixer for at least 10 minutes to 24 hours at a temperature from 20 degrees Celsius to 50 degrees Celsius forming a high viscosity solution or until a homogenous solution is created. In embodiments the mixing can be performed in a short window of time, such as from 10 minutes to 240 minutes.

As a third step, a second portion of ethylene propylene diene terpolymer (EPDM) is added to the high viscosity solution.

The second portion of ethylene propylene diene terpolymer (EPDM) is 0.1 weight percent to 50 weight percent of the total amount of ethylene propylene diene terpolymer (EPDM) in the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

Next, a second portion of solvent is added to the high viscosity solution wherein the second portion of solvent is 33 weight percent to 67 weight percent of the total amount of solvent in the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

As a fifth step, the high viscosity solution is blended for 10 minutes to 12 hours at a temperature from 20 degrees Celsius to 50 degrees Celsius forming a low viscosity liquid intermediate rubber formulation, such as from 10 minutes to 120 minutes.

As a sixth step, a co-agent is added to the low viscosity liquid intermediate rubber formulation, wherein the co-agent is 0.01 weight percent to 10 weight percent based on a total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

The co-agent can be an acrylate, a triallyl cyanurate, a polybutadiene, and a phenylenedimaleimide.

As a seventh step, a peroxide is added to the low viscosity liquid intermediate rubber formulation, wherein the peroxide is 0.1 weight percent to 15 weight percent based on a total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter of a peroxide to the low viscosity liquid intermediate rubber formulation.

The peroxide can be a peroxyketal, a peroxyester, a dialkyl peroxide, a peroxy carbonate, and an azo initiator.

As an eighth step, the low viscosity liquid intermediate rubber formulation is blended at a low shear for 10 minutes to 12 hours at a temperature from 20 degrees Celsius to 50 degrees Celsius forming the ethylene propylene diene terpolymer component. The blending can be for a less time, such as from 10 minutes to 120 minutes.

As a ninth step, the method involves blending in a closed vessel forming a catalyst component, by adding from 0.1 weight percent to 10 weight percent of a metal drier based pm a total amount of a metal drier based in the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

As the tenth step, a third portion of solvent, namely from 1 weight percent to 5 weight percent of solvent is added to the metal drier, the solvent weight percent being a total amount of a solvent based on the total weight of the of the solvent in the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

The solvent of the tenth step can be the same solvent as in the third step and the first step. Mineral spirits is a usable solvent for these three steps.

The metal drier can be a metal carboxylate, or a metal alkoxide.

The solvent can be an aliphatic solvent, an aromatic solvent, or a plant-based solvent.

As a eleventh step, the ethylene propylene diene terpolymer component and catalyst component are blended together forming a blend, prior to application on a substrate.

The two components are blended using a weight ratio from 250:1 to 10:1 of the ethylene propylene diene terpolymer component to the catalyst component, the blend curing on the substrate without addition of another curative, resulting in a low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation, a volatile organic compounds content less than 450 grams per liter, a tensile strength greater than 250 psi, an elongation greater than 50 percent, and a Shore A hardness from 40 to 70.

In embodiments, the first portion of ethylene propylene diene terpolymer (EPDM) can have a different molecular weight than the second portion of ethylene propylene diene terpolymer (EPDM).

In embodiments, the method can also involve adding to the ethylene propylene diene terpolymer component 50 weight percent to 99 weight percent of a pigment based on a total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

The amount of the pigment added represents a total weight percent of pigment in the high viscosity solution, and blending the pigment to a particle dispersion from 4 to 8 units on the Hegman scale.

In embodiments, the method can also involve adding to the ethylene propylene diene terpolymer component 50 weight percent to 99 weight percent of a filler based on a total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

The amount of the filler added represent a total weight percent of filler in the high viscosity solution; and blending the filler to a particle dispersion from 4 to 8 units on the Hegman scale.

In embodiments, the method can also involve adding to the ethylene propylene diene terpolymer component 0.1 weight percent to 10 weight percent of an additive based on a total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

In embodiments, the additive can be a hindered phenolic stabilizer or a hindered amine ultraviolet stabilizer.

In embodiments, the method can also involve adding 0.1 weight percent to 10 weight percent of an adhesion promoter to the ethylene propylene diene terpolymer component based on the total weight low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

In embodiments, the adhesion promoter can be a zinc diacrylate or zinc dimethacrylate.

In embodiments, the method can also involve adding 0.1 weight percent to 10 weight percent of a pigment dispersant to the ethylene propylene diene terpolymer component based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

In embodiments, the pigment dispersant can be 1 methoxy-2-propylacetate.

In embodiments, the method can also involve adding 0.1 weight percent to 10 weight percent of an anti-settling agent to the ethylene propylene diene terpolymer component based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter, after the second portion of ethylene propylene diene terpolymer (EPDM) is added to the high viscosity solution.

In embodiments, the anti-settling agent can be a hydroxyl ethyl cellulose or a fumed silica.

In embodiments, the method can also involve adding 0.1 weight percent to 10 weight percent of a defoamer to the ethylene propylene diene terpolymer component based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

In embodiments, the defoamer can be a polymethyl alkyl siloxane, a modified polysiloxane, or a polymethylsiloxane in a solvent.

In embodiments, the method can also involve adding 0.1 weight percent to 10 weight percent of an air release agent to the ethylene propylene diene terpolymer component based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter after the second portion of ethylene propylene diene terpolymer (EPDM) is added to the high viscosity solution.

In embodiments, the air release agent can be a mineral oil, a paraffinic oil, a silicone oil, or a similar oil.

In embodiments, the method can also involve adding 0.1 weight percent to 30 weight percent of a flame retardant to the ethylene propylene diene terpolymer component based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

In embodiments, the flame retardant can be an alumina trihydrate, by adding with a pigment, a filler, or an additive to ethylene propylene diene terpolymer component or after the second portion of ethylene propylene diene terpolymer is added to the ethylene propylene diene terpolymer component.

In embodiments, the method can also involve adding 0.1 weight percent to 12 weight percent of a wetting agent to the ethylene propylene diene terpolymer component based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.

In embodiments, the wetting agent can be a silicone polyacrylate copolymer in solvent or a solvent-free polyether modified dimethylpolysiloxane.

In embodiments, the method can also involve adding 0.1 weight percent to 5 weight percent of a biocide to the ethylene propylene diene terpolymer component based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter, after the second portion of ethylene propylene diene terpolymer (EPDM) is added to the high viscosity solution.

In embodiments, the biocide can be a methylchloroisothiazolinone.

In embodiments, the method can also involve adding 0.1 weight percent to 30 weight percent of a low molecular weight non-volatile plasticizer to the ethylene propylene diene terpolymer component based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter, after the second portion of solvent is added to the high viscosity solution.

In embodiments, the plasticizer can be a paraffinic oil, a naphthenic oil, a plant based oil, a diester oil, a silicone oil, a mineral oil, a low molecular weight polyalphaolefin, or combinations thereof.

In embodiments, the solvents can be mineral spirits or hexamethyldi-siloxane.

While these embodiments have been described with emphasis on the embodiments, it should be understood that within the scope of the appended claims, the embodiments might be practiced other than as specifically described herein. 

What is claimed is:
 1. A low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter, comprising: a. an ethylene propylene diene terpolymer component comprising: (i) a first portion of ethylene propylene diene terpolymer (EPDM), wherein the ethylene propylene diene terpolymer (EPDM) is 50 weight percent to 99 weight percent of a total amount of the ethylene propylene diene terpolymer (EPDM) used in the high solids low volatile organic compounds durable curable waterproof liquid rubber formulation, and (ii) a first portion of solvent wherein the first portion of solvent is 33 weight percent to 67 weight percent of a total amount of solvent used in the high solids low volatile organic compounds durable curable waterproof liquid rubber formulation; (iii) a second portion of ethylene propylene diene terpolymer (EPDM), wherein the second portion of ethylene propylene diene terpolymer (EPDM) is 0.1 weight percent to 50 weight percent of the total amount of ethylene propylene diene terpolymer (EPDM) in the high solids low volatile organic compounds durable curable waterproof liquid rubber formulation; (iv) a second portion of solvent, wherein the second portion of solvent is 33 weight percent to 67 weight percent of the total amount of solvent in the high solids low volatile organic compounds durable curable waterproof liquid rubber formulation; (v) 0.01 weight percent to 10 weight percent of a co-agent, wherein the weight percent of the co-agent is based on a total weight of the high solids low volatile organic compounds durable curable waterproof liquid rubber formulation and, wherein the co-agent comprises at least one of: an acrylate, a triallyl cyanurate, a polybutadiene, and a phenylenedimaleimide; and (vi) 0.1 weight percent to 15 weight percent of a peroxide, wherein the weight percent of the peroxide is based on a total weight of the high solids low volatile organic compounds durable curable waterproof liquid rubber formulation, and wherein the peroxide comprises at least one of: a peroxyketal, a peroxyester, a dialkyl peroxide, a peroxy carbonate, and an azo initiator; b. a catalyst component comprising: (i) 0.1 weight percent to 10 weight percent of a metal drier based on the total weight of the high solids low volatile organic compounds durable curable waterproof liquid rubber formulation, and wherein the metal drier comprises at least one of: a metal carboxylate, and a metal alkoxide; and (ii) 1.0 weight percent to 5 weight percent of a solvent based on the total weight of the of the solvent in the high solids low volatile organic compounds durable curable waterproof liquid rubber formulation, and wherein the solvent comprises at least one of: an aliphatic solvent, an aromatic solvent, and a plant-based solvent; and the ethylene propylene diene terpolymer component and catalyst component forming a blend, with a weight ratio from 250:1 to 10:1 of the ethylene propylene diene terpolymer component to the catalyst component, and wherein the blend is adapted to cure on a substrate without addition of another curative, producing a low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter with a tensile strength greater than 250 psi, an elongation greater than 50 percent, and a Shore A hardness from 40 to
 70. 2. The formulation of claim 1, wherein the first portion of ethylene propylene diene terpolymer (EPDM) has a different molecular weight than the second portion of ethylene propylene diene terpolymer (EPDM).
 3. The formulation of claim 1, further comprising 50 weight percent to 99 weight percent of a pigment based on a total weight of the high solids low volatile organic compounds durable curable waterproof liquid rubber formulation, wherein the amount of the pigment represent a total weight percent of pigment; and the pigment has a particle dispersion from 4 to 8 units on the Hegman scale.
 4. The formulation of claim 1, further comprising 50 weight percent to 99 weight percent of a filler based on a total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter wherein the amount of the filler added represent a total weight percent of filler; and the filler has a particle dispersion from 4 to 8 units on the Hegman scale.
 5. The formulation of claim 1, further comprising 0.1 weight percent to 10 weight percent of an additive based on a total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter and the additive is at least one of: a hindered phenolic stabilizer or a hindered amine ultraviolet stabilizer.
 6. The formulation of claim 1, further comprising 0.1 weight percent to 10 weight percent of an adhesion promoter based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.
 7. The formulation of claim 1, further comprising 0.1 weight percent to 10 weight percent of a pigment dispersant based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.
 8. The formulation of claim 1, further comprising 0.1 weight percent to 10 weight percent of an anti-settling agent based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.
 9. The formulation of claim 1, further comprising 0.1 weight percent to 10 weight percent of a defoamer based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.
 10. The formulation of claim 1, further comprising 0.1 weight percent to 10 weight percent of an air release agent based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter wherein the air release agent comprises at least one of: a mineral oil, a paraffinic oil, a silicone oil, or a similar oil.
 11. The formulation of claim 1, further comprising 0.1 weight percent to 30 weight percent of a flame retardant based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.
 12. The formulation of claim 1, further comprising 0.1 weight percent to 12 weight percent of a wetting agent based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.
 13. The formulation of claim 1, further comprising 0.1 weight percent to 5 weight percent of a biocide based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter.
 14. The formulation of claim 1, further comprising 0.1 weight percent to 30 weight percent of a low molecular weight non-volatile plasticizer based on the total weight of the low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter, wherein the plasticizer comprises: a paraffinic oil, a naphthenic oil, a plant based oil, a diester oil, a silicone oil, a mineral oil, a low molecular weight polyalphaolefin, or combinations thereof.
 15. The formulation of claim 1, wherein the first portion of solvent and the second portion of solvent are selected from the group: mineral spirits and hexamethyldi-siloxane. 